The Nature of the Hydrogen Bond : Outline of a Comprehensive Hydrogen Bond Theory

The Nature of the Hydrogen Bond : Outline of a Comprehensive Hydrogen Bond Theory

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Key Features
  • Format: Paperback
  • Number of Pages: 336 pages
  • Dimensions: 156 x 232 x 20mm
  • Weight: 599.99g
  • Publication date: 01 Jul 2013
  • Publisher: Oxford University Press
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Hydrogen bond (H-bond) effects are known: it makes sea water liquid, joins cellulose microfibrils in trees, shapes DNA into genes and polypeptide chains into wool, hair, muscles or enzymes. Its true nature is less known and we may still wonder why O-H...O bond energies range from less than 1 to more than 30 kcal/mol without apparent reason. This H-bond puzzle is re-examined here from its very beginning on the ground of an inclusive compilation of experimental H-bond energies and geometries. New concepts emerge from this analysis: new classes of systematically strong H-bonds (CAHBs and RAHBs: charge- and resonance-assisted H-bonds); full H-bond classification in six classes (the six chemical leitmotifs); and assessment of the covalent nature of strong H-bonds. This leads to three distinct but inter-consistent models able to rationalize the H-bond and predict its strength, based on classical VB theory, matching of donor-acceptor acid-base parameters (PA or pKa), or shape of the H-bond proton-transfer pathway. Applications survey a number of systems where strong H-bonds play an important functional role, namely drug-receptor binding, enzymatic catalysis, ion-transport through cell membranes, crystal design and molecular mechanisms of functional materials.

Key Features
  • Format: Paperback
  • Number of Pages: 336 pages
  • Dimensions: 156 x 232 x 20mm
  • Weight: 599.99g
  • Publication date: 01 Jul 2013
  • Publisher: Oxford University Press
  • Publication City/Country: Oxford, United Kingdom
  • Language: English
  • Edition statement: Reprint
  • Illustrations note: 120 b/w line illustrations and 6 page colour plate section
  • ISBN10: 0199673470
  • ISBN13: 9780199673476
Specifications of The Nature of the Hydrogen Bond : Outline of a Comprehensive Hydrogen Bond Theory
SKU
JU030BKAJ82HNAFAMZ
Model
9780199673476
Author
Gastone Gilli
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